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2048  |   Clin Case Rep. 2021;9:2048–2052. wileyonlinelibrary.com/journal/ccr3 1  |  INTRODUCTION We report a 56-­year-­old man with methemoglobinemia and hemolytic anemia, secondary to fava bean ingestion. Methylene blue administration worsened the hemolysis as he was G6PD deficient but not diagnosed before. We have dis- cussed the mechanism of hemolysis in such patients and the management of such cases. Hemolytic anemia, a form of anemia that causes premature rupture of erythrocytes, accounts for five percent of anemias.1 Glucose-­6-­phosphate dehydrogenase (G6PD) deficiency is a well-­known cause of hemolysis and currently affects around 400 000 000 individuals globally. It has a notable prevalence in African, Asian, and Mediterranean countries.2 Favism is a common trigger of oxidative stress in G6PD deficient people, which can lead to hemolysis. Additionally, fava bean ingestion can cause methemoglobinemia.3 Methemoglobin is an abnormal variation in the hemoglobin in which the ferrous (Fe2+) iron in heme is oxidized to the ferric (Fe3+) state. The condition is usu- ally acquired, secondary to oxidative stress in the body such as favism or infections, but can rarely be congenital.4 The first-­line treatment for methemoglobinemia is methylene blue. However, in G6PD deficient patients, methylene blue can potentiate hemo- lysis because of its oxidative effects.3 It is vital to take a detailed history of patients presenting with hemolysis to identify the po- tential causes and avoid any additional oxidative stress. Received: 7 October 2020  |  Revised: 3 February 2021  |  Accepted: 4 February 2021 DOI: 10.1002/ccr3.3941 C A S E R E P O R T Favism-­induced methemoglobinemia in a G6PD deficient male with a subsequent hemolytic cascade, a therapeutic challenge: Case report and review of literature Fateen Ata1   | Saad Javed2   | Bassam Muthanna1   | Ines dakhlia1  | Ammara Bint I Bilal3   | Motwakil Musa1  | Mashuk Uddin1  | Mohamed A. Yassin4 This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. © 2021 The Authors. Clinical Case Reports published by John Wiley & Sons Ltd. 1Department of Internal Medicine, Hamad Medical Corporation, Doha, Qatar 2Department of Internal Medicine, Jinnah Hospital, Allama Iqbal Medical College, Lahore, Pakistan 3Department of Radiology, Hamad Medical Corporation, Doha, Qatar 4Department of Hematology, National Center for Cancer Care & Research, Hamad Medical Corporation, Doha, Qatar Correspondence Bassam Muthanna, Internal Medicine, Hamad General Hospital, PO box 3050, Doha, Qatar. Email: [email protected] Funding information The publication of this manuscript is supported by Qatar National Library (QNL) Abstract The co-­occurrence of acute hemolysis and methemoglobinemia secondary to favism in G6PD deficient individuals is rare. Identifying it promptly is of high clinical signif- icance as treating methemoglobinemia (with methylene blue) can worsen hemolysis. K E Y W O R D S fava beans, Favism, G6PD, glucose-­6-­phosphate dehydrogenase, Hemolysis, methemoglobinemia      |  2049 ATA et al. 2  |  CASE PRESENTATION A 56-­years-­old Qatari man, known to have type-­II diabetes mellitus and hypertension, presented with a 5-­day history of progressive dyspnea and dizziness. He also had a 3-­day history of mild hematuria and one episode of minimal non- bloody vomiting. The patient had no recent infection and no exposure to new medications. He is married (nonconsanguin- eous), a smoker (5 cigarettes per day) but nonalcoholic with no history of illicit drug use. Upon examination, he was vitally stable (afebrile, Blood pressure 136/76  mm  Hg, heart rate 93 beats per minute) other than an oxygen saturation (SPO2) of 70% on room air. On examination, he had pallor and jaundice. The rest of the physical examination was unremarkable. Arterial blood gas (ABG) analysis revealed SPO2 of 101% and a methemoglobin (MetHB) level of 5.6% (Table 1). The patient was initiated on supplemental oxygen, but his SPO2 remained low. Because of a high MetHgb level, a provisional diagnosis of methemo- globinemia was made, and he received methylene blue intra- venously (IV) 80 mg while in the emergency department. A complete blood analysis revealed low hemoglobin (Hgb) of 9.9 gm/dL, secondary to hemolysis (Table 1, Figure 1). Chest x-­ray and electrocardiogram were unremarkable. A urine dip- stick analysis did not reveal significant blood or protein. A repeated Hgb level after 24 hours showed a further drop to 7 gm/dL. As he was symptomatic, two units of packed red blood cells (RBC) were transfused. Unexpectedly, his Hgb continued to drop further (Figure 1). Ongoing hemolysis was evident, and a detailed history was retaken to identify the cause of hemolysis. The patient revealed an intake of large amounts of fava beans, which preceded his symptoms. He had a history of eating fava beans in small amounts before without experiencing any symptoms. However, this time, the intake was considerably larger (six fava beans containing sandwiches). Because of suspicion of favism-­induced hemo- lysis, a G6PD level was sent, which came low (Table 1). At this point, he was diagnosed with G6PD deficiency, aggra- vated by the ingestion of a large number of fava beans. His hemolysis was worsened by methylene blue, which was evi- dent by a progressive drop in Hgb. The patient was kept in the medical ward under close obser- vation. He received a total of 3000 mg of IV Vitamin C in two di- vided doses. After 2 days, his SPO2 improved to 100% on room air, and Hgb improved gradually to 11 gm/dL on the fifth day (Figure 1). He was discharged as he became asymptomatic on day five with a follow-­up in the acute medical assessment clinic. 3  |  FOLLOW-­UP Follow-­up lab work showed near-­normal Hgb (12 gm/dL), normal bilirubin, and liver enzymes. The patient did not have any residual dyspnea. There was no jaundice, and his hema- turia had resolved. He was discharged from the clinic with clear instructions about his diagnosis. He was also counseled to avoid fava beans in the future. He was using aspirin as pri- mary prevention of cardiovascular disease and was advised to discontinue it to avoid oxidative stress. The patient was offered genetic testing of G6PD at the follow-­up visit in the genetics clinic, which he refused. 4  |  DISCUSSION Glucose-­6-­phosphate dehydrogenase (G6PD) deficiency is the most prevalent blood cell disorder in humans.5 It is an X-­linked genetic disorder caused by a chromosome X defect (band X q28).6 It is usually diagnosed when patients present TABLE 1  Clinical features of the patient Hematological parameters Patient code Normal range WBC count 31000 4.5-­11 *103/μL Platelets 515 150-­400 ×103/μL MCV 98.7 83-­101 fL MCHC 32.9 31.5-­34.5 gm/dL RI 2.47 >2 PO2 on ABG 524 83-­108 mm Hg MetHgb 5.6% <1.6% Indirect bilirubin 60 <13 μmol/L LDH Hemolyzed 135-­225 U/L Haptoglobin 15 30-­200 mg/dL G6P6D quantity 23 224-­ 517 mU/109RBC PS Bite cells, blister cells, left shift –­ Carboxy Hgb 3.3% Nonsmoker: <1.5% of Hgb Smokers: <1.5%-­ 5.0% of Hgb HgbE HBA:96, HBA2:2.6, HBS:0, HBF:1, HBH: absent HBA:95.8-­98, HBA2:2-­3.3, HBS:0, HBF:0-­0.9, HBH: absent CRP 67 0-­5 mg/L Abbreviations: CRP, c-­reactive protein; Hgb, hemoglobin; HgbE, hemoglobin electrophoresis; LDH, lactate dehydrogenase; MCHC, mean corpuscular hemoglobin concentration; MCV, Mean corpuscular volume; MetHgb, methemoglobin; PS, peripheral smear; RI, reticulocyte index; WBC, white blood cell. 2050  |      ATA et al. with signs and symptoms of hemolytic anemia, secondary to oxidative stress. It is usually triggered by infections, fava beans, and certain medications.7 Various screening tests are available to detect G6PD deficiency, and the diagnosis is usually con- firmed by quantitative measurement of nicotinamide adenine dinucleotide phosphate (NADPH).8 The primary differential diagnoses of G6PD deficiency are other causes of hemolysis. In malaria-­endemic areas, malaria is one of the differentials of G6PD hemolysis. Other causes of inherited and acquired hemo- lytic anemias need to be considered while diagnosing G6PD deficiency-­induced hemolytic anemia.9 Genetic testing can be carried out via polymerase chain reaction; however, it is usually not routinely performed and limited to challenging situations and atypical presentations.9 Treatment of acute episodes of he- molysis is by transfusion and, more importantly, eliminating the cause of oxidative stress.10 On the other hand, methemoglobinemia is a hemoglobin disorder where ferrous (Fe2+) iron in heme is oxidized to the ferric (Fe3+) state. It is usually acquired, secondary to oxidative stress in the body, but can rarely be congenital.4 Physiologically, various enzyme systems such as NADH methemoglobin reductase, NADPH methemoglobin reduc- tase, ascorbic acid, and glutathione reductase systems keep a check on the accumulation of methemoglobin in the blood.11 FIGURE 1  Trend of hemoglobin of the patient throughout the hospital stay FIGURE 2  Mechanism of reduction of methemoglobin to hemoglobin by methylene blue; concept taken from Percy MJ et al15      |  2051 ATA et al. However, there are instances where these mechanisms are in- sufficient to counter the conversion of hemoglobin to methe- moglobin, consequently promoting an oxidative state in the body. This can be either due to the overproduction of methe- moglobin or under conversion to hemoglobin due to unavail- able enzyme mechanisms. The former can be secondary to exposure to certain drugs, chemicals, or food items but can sometimes be hereditary.12 The inability of enzyme systems to counteract methemoglobin can be secondary to enzyme deficiencies, such as G6PD deficiency. Usually, the patients typically have a low SPO2 on pulse oximeters but a falsely high SPO2 on arterial blood gas- ses (ABG).13 The treatment depends on the level of met- hemoglobin in the body and symptoms. The first step is to remove any possible precipitator if present immediately. The treatment of choice for symptomatic or asymptom- atic patients with a level of methemoglobin >30 percent is methylene blue (1-­2 mg/kg).14 Methylene blue is reduced to leuko-­methylene blue via NADPH-­dependent methe- moglobin reductase. This, in turn, reduces methemoglobin back to hemoglobin, hence correcting the abnormality 15 (Figure 2). Rarely, patients can present with co-­occurrence of met- hemoglobinemia and G6PD deficiency.3,16-­19 In such cases, extreme caution is required while administering methylene blue as they do not have sufficient NADPH levels to reduce it. Otherwise, a cascade of oxidative hemolysis ensues sec- ondary to underlying G6PD deficiency, resulting in a vicious cycle of further methemoglobinemia.11 The most frequent cause of this co-­occurrence reported in the literature is the ingestion of fava beans, which can in- duce methemoglobinemia and potentiate G6PD deficiency simultaneously.3,16-­19 All the reported cases in the litera- ture are male, with a median age of 6 years (range 1-­56). All of them were newly diagnosed with G6PD deficiency upon presentation with MethHgb. Median Hgb was 8 gm/ dL (4.6-­9.9) and median MetHgb was 8% (5.6-­35). One pa- tient (our patient) received methylene blue, and 3 received Vitamin C. All of them recovered and were discharged. Our patient was also male and had taken a full meal consisting of fava beans before presenting. Although his methemo- globin level was 5.6 percent, he was given methylene blue due to his symptoms, which worsened his hemolytic ane- mia (Table 2). Interestingly, our patient had a history of favism in the past without developing any symptoms. Only this time, he ate a larger amount of fava beans, which led to hemolysis and methemoglobinemia. Hence, while treating methemo- globinemia patients, one should be vigilant that a history of fava beans ingestion without any symptoms does not rule out G6PD deficiency. It depends upon the number of beans in- gested over a certain period.20 5  |  CONCLUSION Favism is a rare cause of the co-­occurrence of methemo- globinemia and hemolysis in G6PD deficient individuals. The severity of hemolysis in G6PD deficient individuals is dependent on the number of fava beans ingested. It is vital to identify the presence of G6PD deficiency in patients present- ing with methemoglobinemia, as the initiation of methylene blue in such individuals can result in a cascade of oxidative hemolysis. TABLE 2  Reported cases of methemoglobinemia and G6PD deficiency secondary to favism Case number Patients' age, sex Nationality G6PD deficiency Type Hgb (gm/dL) presentation/lowest MetHgb Methylene blue Vit C Outcome Case 1 16 43 y, male Albanian New diagnosis NA 8/NA 8% No Yes Discharged Case 2 18 6 y, male Algerian New diagnosis G6PD376G/202A 9.2/6 7.6% No No Discharged Case 3 19 30 y, male Nepalese New diagnosis NA 8.4/5.9 35% No Yes Discharged Case 4 3 1 y, male Afghan New diagnosis NA 6.2/6.2 6.2% No No Discharged Case 5 17 1 y, male Iraqi New diagnosis NA 6.9/NA 11.4% No No Discharged Case 6 17 6 y, male Iraqi New diagnosis NA 4.6/NA 14.9% No No Discharged Our case 56 y, male Qatari New diagnosis NA 9.9/6.5 5.6% Yes Yes Discharged Abbreviations: G6PD, Glucose-­6-­phosphate dehydrogenase; Hgb, Hemoglobin; MetHgb (normal 0%-­1.5%), Methemoglobin. 2052  |      ATA et al. ACKNOWLEDGMENTS Authors would like to thank Dr Percy MJ for permitting reproduction of the Figure 2. This article is available as a preprint with the following link: Favism induced methe- moglobinemia in a G6PD deficient male with a subsequent hemolytic cascade, a therapeutic challenge: case report and review of literature -­ Authorea CONFLICT OF INTEREST All authors declare no potential conflicts of interest to dis- close related to the publication of this case series. AUTHOR CONTRIBUTIONS FA, BM: Conceptualized the data. BM: Consented the pa- tient. FA, AB, SJ, ID, MM, MU, MY: Reviewed the litera- ture. FA, BM, AB, SJ, ID: Wrote the manuscript. FA, AB: Collected the data. AB: Took part in writing and images ra- diologically. FA, MU, MY: Modified and critically reviewed the article. FA, AB, SJ, ID, MM, MU, MY: Reviewed finally and approved the article. CONSENT Written informed consent was obtained from the patient for publication of this case report and accompanying images. ORCID Fateen Ata  https://orcid.org/0000-0001-7121-8574 Saad Javed  https://orcid.org/0000-0002-7510-2381 Bassam Muthanna  https://orcid. org/0000-0002-9594-0964 Ammara Bint I Bilal  https://orcid. org/0000-0002-0219-1678 Mohamed A. Yassin  https://orcid. org/0000-0002-1144-8076 REFERENCES 1. Liebman HA, Weitz IC. Autoimmune hemolytic anemia. Med Clin North Am. 2017;101(2):351-­359. 2. Nkhoma ET, Poole C, Vannappagari V, Hall SA, Beutler E. The global prevalence of glucose-­6-­phosphate dehydrogenase defi- ciency: a systematic review and meta-­analysis. Blood Cells Mol Dis. 2009;42(3):267-­278. 3. Schuurman M, van Waardenburg D, Da Costa J, Niemarkt H, Leroy P. Severe hemolysis and methemoglobinemia following fava beans ingestion in glucose-­6-­phosphatase dehydrogenase deficiency: case report and literature review. Eur J Pediatr. 2009;168(7):779-­782. 4. Soliman DS, Yassin M. Congenital methemoglobinemia misdiag- nosed as polycythemia vera: case report and review of literature. 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